The [(μ3‐WSe4)3(μ3‐Se)2 (Cu3)2]4− Anion, an Inorganic Cluster with a Pin wheel Shape

Christopher C. Christuk; Mohammad A. Ansari; James A. Ibers

doi:10.1002/anie.199214771

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The [(μ₃‐WSe₄)₃(μ₃‐Se)₂ (Cu₃)₂]⁴⁻ Anion, an Inorganic Cluster with a Pin wheel Shape

Christopher C. Christuk Mohammad A. Ansari James A. Ibers

Year: 1992 Journal: Angewandte Chemie International Edition in English Vol: 31 (11)Pages: 1477-1478

DOI: 10.1002/anie.199214771

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Abstract

A structure incorporating two eclipsed Cu3 triangles, three bridging μ3-WSe units, and two capping μ3-Se atoms is formed from a cubane-like CuSeW cluster on treatment with Li2Se. This product pictured here (one Se atom is omitted at each W atom) exemplifies one of the structural possibilities for the little-studied selenidometalates.

Keywords:

Cluster (spacecraft) Ion Crystallography Atom (system on chip) Product (mathematics) Chemistry Cubane Crystal structure Physics Atomic physics Geometry Mathematics

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The [(μ₃‐WSe₄)₃(μ₃‐Se)₂ (Cu₃)₂]⁴⁻ Anion, an Inorganic Cluster with a Pin wheel Shape

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