Metal–Organic Frameworks Incorporating Copper‐Complexed Rotaxanes
Ali CoşkunMohamad HmadehGökhan BarınFelipe GándaraQiaowei LiEunwoo ChoiNathan L. StruttDavid B. CordesAlexandra M. Z. SlawinJ. Fraser StoddartJean‐Pierre SauvageOmar M. Yaghi
Abstract
[Image: see text] MOFs on the move: A copper coordinated [2]pseudorotaxanate which reacts with zinc nitrate to form an extended structure, consisting of three-fold interpenetrated networks, retains most of its solution-state chemistry including its ability to undergo electronic switching of some of the copper(I) ions under redox control.
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