JOURNAL ARTICLE
Zeolitic Boron Imidazolate Frameworks with 4‐Connected Octahedral Metal Centers
Fei WangYu‐Bo ShuXianhui BuJian Zhang
Year: 2012 Journal: Chemistry - A European Journal Vol: 18 (38)Pages: 11876-11879 Publisher: Wiley
Abstract
Solvent selection! The organically templated co-assembly between tetrahedral [B(imidazolate)(4)](-) and [Co(ac)](+) units leads to two previously unknown zeolitic boron imidazolate frameworks with ACO and ABW topologies (denoted BIF-22 and BIF-23; e-urea = ethyleneurea), respectively. BIF-22 is chiral and shows interesting CO(2) selectivity over N(2) and CH(4).
Keywords:
Imidazolate Octahedron Zeolitic imidazolate framework Boron Selectivity Tetrahedron Metal-organic framework Chemistry Metal Materials science Crystallography Inorganic chemistry Adsorption Crystal structure Organic chemistry Catalysis
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2.38
FWCI (Field Weighted Citation Impact)
44
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0.88
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Citation History
Topics
Metal-Organic Frameworks: Synthesis and Applications
Physical Sciences → Chemistry → Inorganic Chemistry
Covalent Organic Framework Applications
Physical Sciences → Materials Science → Materials Chemistry
Carbon dioxide utilization in catalysis
Physical Sciences → Chemical Engineering → Process Chemistry and Technology
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