Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis

Douglas W. Stephan

doi:10.1039/b819621d

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Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis

Douglas W. Stephan

Year: 2009 Journal: Dalton Transactions Pages: 3129-3129 Publisher: Royal Society of Chemistry

DOI: 10.1039/b819621d

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Abstract

The combination of Lewis acids and bases that are sterically precluded from forming Lewis acid-base adducts, termed Frustrated Lewis pairs provide a unique route to the activation of small molecules and applications in catalysis.

Keywords:

Frustrated Lewis pair Lewis acids and bases Steric effects Adduct Catalysis Chemistry Molecule Small molecule Combinatorial chemistry Stereochemistry Organic chemistry Biochemistry

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Organoboron and organosilicon chemistry

Physical Sciences → Chemistry → Organic Chemistry

Chemical Synthesis and Reactions

Physical Sciences → Chemistry → Organic Chemistry

Asymmetric Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Frustrated Lewis pairs: a new strategy to small molecule activation and hydrogenation catalysis

Abstract

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