JOURNAL ARTICLE

Schwingungsspektren der käfigstrukturierten Verbindungen P4S3, P4Se3, As4S3 und As4Se3 / Vibrational Spectra of the Cage Compounds P4S3, P4Se3, As4S3 and As4Se3

W. BuesMehmet SomerWolfgang Brockner

Year: 1980 Journal:   Zeitschrift für Naturforschung B Vol: 35 (9)Pages: 1063-1069   Publisher: De Gruyter

Abstract

The vibrational spectra of the cage compounds P4S3, P4Se3 and AS4S3 have been recorded in the solid and the molten state. The vibrational spectra of crystalline As4Se3, which decomposes during melting, have been investigated. The frequencies wore assigned using the concept of group frequencies. A new assignment of the Raman frequencies is proposed for P 4 S 3 based on new po­larization data. The frequencies of the arsenic compounds are reported for the first time. The Raman spectra of the molten compounds suggest that the cage structure is retained in the molten state.

Keywords:
Raman spectroscopy Spectral line Chemistry Solid-state Analytical Chemistry (journal) Crystallography Physical chemistry Physics

Metrics

45
Cited By
0.95
FWCI (Field Weighted Citation Impact)
3
Refs
0.74
Citation Normalized Percentile
Is in top 1%
Is in top 10%

Citation History

Topics

Semiconductor materials and interfaces
Physical Sciences →  Physics and Astronomy →  Atomic and Molecular Physics, and Optics
Phase-change materials and chalcogenides
Physical Sciences →  Materials Science →  Materials Chemistry
Synthesis and characterization of novel inorganic/organometallic compounds
Physical Sciences →  Chemistry →  Inorganic Chemistry

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