Benzene in a new face-capping bonding mode: molecular structures of [Ru6C(CO)11(µ3-η2: η2:η2-C6H6)(η6-C6H6)] and [Os3(CO)9(µ3-η2: η2:η2-C6H6)]

Pilar Gómez‐Sal; Brian F. G. Johnson; Jack Lewis; Paul R. Raithby; Anthony Wright

doi:10.1039/c39850001682

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Benzene in a new face-capping bonding mode: molecular structures of [Ru₆C(CO)₁₁(µ₃-η²: η²:η²-C₆H₆)(η⁶-C₆H₆)] and [Os₃(CO)₉(µ₃-η²: η²:η²-C₆H₆)]

Pilar Gómez‐Sal Brian F. G. Johnson Jack Lewis Paul R. Raithby Anthony Wright

Year: 1985 Journal: Journal of the Chemical Society Chemical Communications Pages: 1682-1684 Publisher: Royal Society of Chemistry

DOI: 10.1039/c39850001682

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Abstract

A new co-ordination mode for benzene ligands in cluster complexes, in which the ring is symmetrically placed above a metal triangle has been crystallographically established in the carbonyl complexes [Ru6C(CO)11(µ3-η2: η2:η2-C6H6)(η6-C6H6)] and [Os3(CO)9(µ3-η2: η2:η2-C6H6)].

Keywords:

Benzene Chemistry Crystallography Metal Cluster (spacecraft) Ring (chemistry) Molecule Stereochemistry Organic chemistry

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Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Coordination Chemistry and Organometallics

Physical Sciences → Chemistry → Organic Chemistry

Radioactive element chemistry and processing

Physical Sciences → Chemistry → Inorganic Chemistry

Benzene in a new face-capping bonding mode: molecular structures of [Ru₆C(CO)₁₁(µ₃-η²: η²:η²-C₆H₆)(η⁶-C₆H₆)] and [Os₃(CO)₉(µ₃-η²: η²:η²-C₆H₆)]

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