Iron tetrasulfophthalocyanine immobilized on metal organic framework MIL-101: synthesis, characterization and catalytic properties

Olga V. Zalomaeva; Konstantin A. Kovalenko; Yu. A. Chesalov; Maxim S. Mel’gunov; В. И. Зайковский; В. В. Каичев; Alexander B. Sorokin; Oxana A. Kholdeeva; Vladimir P. Fedin

doi:10.1039/c0dt01474e

JOURNAL ARTICLE

Iron tetrasulfophthalocyanine immobilized on metal organic framework MIL-101: synthesis, characterization and catalytic properties

Olga V. Zalomaeva Konstantin A. Kovalenko Yu. A. Chesalov Maxim S. Mel’gunov В. И. Зайковский В. В. Каичев Alexander B. Sorokin Oxana A. Kholdeeva Vladimir P. Fedin

Year: 2011 Journal: Dalton Transactions Vol: 40 (7)Pages: 1441-1441 Publisher: Royal Society of Chemistry

DOI: 10.1039/c0dt01474e

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Abstract

Iron tetrasulfophthalocyanine (FePcS) has been irreversibly inserted into nanocages of the metal organic framework MIL-101 to give a hybrid material FePcS/MIL-101 which demonstrated a superior catalytic performance in the selective oxidation of aromatic substrates with (t)BuOOH than homogeneous FePcS.

Keywords:

Nanocages Catalysis Metal-organic framework Homogeneous Chemistry Metal Characterization (materials science) Heterogeneous catalysis Inorganic chemistry Combinatorial chemistry Organic chemistry Materials science Nanotechnology Adsorption

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Metal-Organic Frameworks: Synthesis and Applications

Physical Sciences → Chemistry → Inorganic Chemistry

Magnetism in coordination complexes

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Porphyrin and Phthalocyanine Chemistry

Physical Sciences → Materials Science → Materials Chemistry

Iron tetrasulfophthalocyanine immobilized on metal organic framework MIL-101: synthesis, characterization and catalytic properties

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