Schwefelreiche spirozyklische Komplexe: [Zn(S6)2]2–, [Cd(S6)2]2–, [Hg(S6)2]2– und [Hg(S4)2]2– / Sulfur-Rich Spirocyclic Complexes: [Zn(S6)2]2-, [Cd(S6)2]2-, [Hg(S6)2]2- and [Hg(S4)2]2-

Achim Müller; Jürgen Schimanski; Uwe Schimanski; Hartmut Bögge

doi:10.1515/znb-1985-1009

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Schwefelreiche spirozyklische Komplexe: [Zn(S₆)₂]^2–, [Cd(S₆)₂]^2–, [Hg(S₆)₂]^2– und [Hg(S₄)₂]^2– / Sulfur-Rich Spirocyclic Complexes: [Zn(S₆)₂]^2-, [Cd(S₆)₂]^2-, [Hg(S₆)₂]^2- and [Hg(S₄)₂]^2-

Achim Müller Jürgen Schimanski Uwe Schimanski Hartmut Bögge

Year: 1985 Journal: Zeitschrift für Naturforschung B Vol: 40 (10)Pages: 1277-1288 Publisher: De Gruyter

DOI: 10.1515/znb-1985-1009

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Abstract

By reaction of Zn(CH 3 COO) 2 ·2H 2 O. Cd(CH 3 COO) 2 -2H 2 O, or Hg(CH 3 COO) 2 with defined alcoholic polysulfide solutions the crystalline compounds (NEt 4 ) 2 [Hg(S 6 ) 2 ] (1), [(PPh 3 ) 2 N] 2 [Cd(S 6 ) 2 ]·CH 3 CN (2), (PPh 4 ) 2 [Zn(S 6 ) 2 ] (3) and (PPh 4 ) 2 [Hg(S 4 ) 2 ] (4) could be obtained. 1-4 were characterised spectroscopically (IR, Raman, UV/VIS) and by X-ray structure analyses.

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Chemistry X-ray crystallography Raman spectroscopy Zinc Crystallography Analytical Chemistry (journal) Physics Diffraction

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Organometallic Compounds Synthesis and Characterization

Physical Sciences → Chemistry → Organic Chemistry

Inorganic Chemistry and Materials

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