JOURNAL ARTICLE

Methanol electrooxidation on PtRu modified zeolite X

Zorica MojovićTihana MudrinićA. Abu Rabi-StankovićAna Ivanović-ŠašićSanja MarinovićM. ŽunićD. Jovanović

Year: 2013 Journal:   Science of Sintering Vol: 45 (1)Pages: 89-96   Publisher: International Institute for the Science of Sintering, Beograd

Abstract

Zeolite NaX (faujasite type) was used as a support for platinum-ruthenium catalyst. A procedure for thermal decomposition of noble metal acetylacetonates to deposit noble metal clusters on the surface of solid support was adapted by authors to introduce noble metal clusters in zeolite cavities. The effectiveness of this composite material for methanol electrooxidation from alkaline solution was investigated by cyclic voltammetry. The influence of the concentration of supporting electrolyte, scan rate and rotation rate on the reaction of methanol oxidation was investigated. The obtained activity was compared with literature data for similar catalysts.

Keywords:
Noble metal Faujasite Zeolite Methanol Catalysis Platinum Cyclic voltammetry Ruthenium Inorganic chemistry Materials science Thermal decomposition Rhodium Metal Electrolyte Chemistry Electrochemistry Physical chemistry Electrode Metallurgy Organic chemistry

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Topics

Electrocatalysts for Energy Conversion
Physical Sciences →  Energy →  Renewable Energy, Sustainability and the Environment
Fuel Cells and Related Materials
Physical Sciences →  Engineering →  Electrical and Electronic Engineering
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Physical Sciences →  Materials Science →  Materials Chemistry
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