JOURNAL ARTICLE
Some evidence against the existence of the liquid‐liquid transition. III. The evaluation of the Tll event by differential scanning calorimetry
J. ChenC. KowLewis J. FettersD. J. Plazek
Year: 1982 Journal: Journal of Polymer Science Polymer Physics Edition Vol: 20 (9)Pages: 1565-1574 Publisher: Wiley
Abstract
Abstract The liquid‐liquid transition T ll has been examined by using differential scanning calorimetry as the tool of measurement. The results presented show that for the case of polystyrene, the T ll event appears to be an artifact caused by the presence of volatile components. Purified samples of polystyrene, polydienes, and poly(1‐butene) do not show the T ll transition.
Keywords:
Differential scanning calorimetry Polystyrene Artifact (error) Differential (mechanical device) Materials science Liquid liquid Calorimetry Analytical Chemistry (journal) Event (particle physics) Phase transition Polymer chemistry Chemistry Polymer Chromatography Thermodynamics Physics Composite material Computer science
Metrics
34
Cited By
4.20
FWCI (Field Weighted Citation Impact)
32
Refs
0.95
Citation Normalized Percentile
Is in top 1%
Is in top 10%
Citation History
Topics
Polymer crystallization and properties
Physical Sciences → Materials Science → Polymers and Plastics
Material Dynamics and Properties
Physical Sciences → Materials Science → Materials Chemistry
Scientific Research and Discoveries
Physical Sciences → Physics and Astronomy → Statistical and Nonlinear Physics
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