Aminolyse von Cp2ZrCl{P(SiMe3)2} - Synthese und Molekülstruktur von Cp2ZrCl(NHPh) / Aminolysis of Cp2ZrCl{P(SiMe3)2} - Synthesis and Molecular Structure of Cp2ZrCl(NHPh)

Frank Lindenberg; Evamarie Hey‐Hawkins; Gerhard Baum

doi:10.1515/znb-1995-0911

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Aminolyse von Cp₂ZrCl{P(SiMe₃)₂} - Synthese und Molekülstruktur von Cp₂ZrCl(NHPh) / Aminolysis of Cp₂ZrCl{P(SiMe₃)₂} - Synthesis and Molecular Structure of Cp₂ZrCl(NHPh)

Frank Lindenberg Evamarie Hey‐Hawkins Gerhard Baum

Year: 1995 Journal: Zeitschrift für Naturforschung B Vol: 50 (9)Pages: 1359-1361 Publisher: De Gruyter

DOI: 10.1515/znb-1995-0911

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Abstract

Abstract The reaction of Cp 2 ZrCl{P(SiMe 3 ) 2 } with aniline yields the terminal zirconocene phenylamido complex Cp 2 ZrCl(NHPh) (1) and HP(SiMe 3 ) 2 . 1 was characterized spectroscopically (n.m.r., i.r.) and by X-ray structure determination (monoclinic space group P 2 {ln, a - 6.589(2), b = 19.978(3), c = 13.512(2) Å , β = 101.09(2)° (at 200 K)). The NHPh group is planar with Zr -N 2116(10) Å.

Keywords:

Aminolysis Monoclinic crystal system Aniline Chemistry Stereochemistry Medicinal chemistry Crystallography Crystal structure Organic chemistry Catalysis

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Aminolyse von Cp₂ZrCl{P(SiMe₃)₂} - Synthese und Molekülstruktur von Cp₂ZrCl(NHPh) / Aminolysis of Cp₂ZrCl{P(SiMe₃)₂} - Synthesis and Molecular Structure of Cp₂ZrCl(NHPh)

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