A Tri‐Coordinate‐Magnesium Silylamide Complex: {[(CH3)3Si]2N}2MgO(CH2CH2)2OMg{N[Si(CH3)3]2}2

Tzong‐Yih Her; Chung‐Cheng Chang; Gene‐Hsiang Lee; Shie‐Ming Feng; Yu Wang

doi:10.1002/jccs.199300048

ScienceGate Book Chapters

JOURNAL ARTICLE

A Tri‐Coordinate‐Magnesium Silylamide Complex: {[(CH₃)₃Si]₂N}₂MgO(CH₂CH₂)₂OMg{N[Si(CH₃)₃]₂}₂

Tzong‐Yih Her Chung‐Cheng Chang Gene‐Hsiang Lee Shie‐Ming Feng Yu Wang

Year: 1993 Journal: Journal of the Chinese Chemical Society Vol: 40 (3)Pages: 315-317 Publisher: Wiley

DOI: 10.1002/jccs.199300048

Get Full-Text PDF Get Analytical Report

Abstract

Abstract The reaction of diethylmagnesium dioxane adduct solution with 1,1,1,3,3,3‐hexamethyldisilazan ((CH 3 ) 3 SiNHSi(CH 3 ) 3 ) gives {[(CH 3 ) 3 Si] 2 N} 2 MgO(CH 2 CH 2 ) 2 OMg{N[Si(CH 3 ) 3 ] 2 } 2 (1); this alkoxomagnesium silylamide in the solid state contains unprecedented three‐coordinate magnesium and oxygen atoms.

Keywords:

Chemistry Adduct Magnesium Solid-state Oxygen atom Crystallography Physical chemistry Inorganic chemistry Medicinal chemistry Molecule Organic chemistry

Metrics

Cited By

0.00

FWCI (Field Weighted Citation Impact)

Refs

0.21

Citation Normalized Percentile

Is in top 1%

Is in top 10%

Citation History

Topics

Silicone and Siloxane Chemistry

Physical Sciences → Materials Science → Materials Chemistry

Synthesis and characterization of novel inorganic/organometallic compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Organoboron and organosilicon chemistry

Physical Sciences → Chemistry → Organic Chemistry

A Tri‐Coordinate‐Magnesium Silylamide Complex: {[(CH₃)₃Si]₂N}₂MgO(CH₂CH₂)₂OMg{N[Si(CH₃)₃]₂}₂

Abstract

Metrics

Citation History

Topics

Related Documents

Synthese und Kristallstruktur von Mg[Si(CH₃)₃]₂ · (CH₃)₂NCH₂CH₂CH₂N(CH₃)₂ / Synthesis and Crystal Structure of Mg[Si(CH₃)₃]₂ · (CH₃)₂NCH₂CH₂CH₂N(CH₃)₂

Unimolecular reactions of isolated organic ions: reactions of the immonium ions CH₂N⁺(CH₃)CH(CH₃)₂, CH₂N⁺(CH₃)CH₂CH₂CH₃and CH₂N⁺(CH₂CH₂CH₃)₂

LE MÉTHYLE₃HEPTANE CH₃ ‐ CH₂ ‐ CH ‐ CH₂ ‐ CH₂ ‐ CH₂ ‐ CH₃ | CH₃ (on MÉTHYL ‐ ÉTHYL ‐ BUTYLMÉTHANE)

Crystal structure of 4,5,6-tris(dimethylamino)-1,2,3-triazine,(N₃C₃)N(CH₃)₂(CH₃)₂N(CH₃)₂N(CH₃)₂

Alkylsulfonylhydroxylamine CH₃(CH₂)_nSO₂NH0H (n = 1, 2, 3) / Alkylsulfonyl Hydroxylamines CH₃(CH₂)_nSO₂NH0H ( » = 1. 2. 3)

A Tri‐Coordinate‐Magnesium Silylamide Complex: {[(CH3)3Si]2N}2MgO(CH2CH2)2OMg{N[Si(CH3)3]2}2

Abstract

Metrics

Citation History

Topics

Related Documents

Synthese und Kristallstruktur von Mg[Si(CH3)3]2 · (CH3)2NCH2CH2CH2N(CH3)2 / Synthesis and Crystal Structure of Mg[Si(CH3)3]2 · (CH3)2NCH2CH2CH2N(CH3)2

Unimolecular reactions of isolated organic ions: reactions of the immonium ions CH2N+(CH3)CH(CH3)2, CH2N+(CH3)CH2CH2CH3and CH2N+(CH2CH2CH3)2

LE MÉTHYLE3HEPTANE CH3 ‐ CH2 ‐ CH ‐ CH2 ‐ CH2 ‐ CH2 ‐ CH3 | CH3 (on MÉTHYL ‐ ÉTHYL ‐ BUTYLMÉTHANE)

Crystal structure of 4,5,6-tris(dimethylamino)-1,2,3-triazine,(N3C3)N(CH3)2(CH3)2N(CH3)2N(CH3)2

Alkylsulfonylhydroxylamine CH3(CH2)nSO2NH0H (n = 1, 2, 3) / Alkylsulfonyl Hydroxylamines CH3(CH2)nSO2NH0H ( » = 1. 2. 3)

A Tri‐Coordinate‐Magnesium Silylamide Complex: {[(CH₃)₃Si]₂N}₂MgO(CH₂CH₂)₂OMg{N[Si(CH₃)₃]₂}₂

Synthese und Kristallstruktur von Mg[Si(CH₃)₃]₂ · (CH₃)₂NCH₂CH₂CH₂N(CH₃)₂ / Synthesis and Crystal Structure of Mg[Si(CH₃)₃]₂ · (CH₃)₂NCH₂CH₂CH₂N(CH₃)₂

Unimolecular reactions of isolated organic ions: reactions of the immonium ions CH₂N⁺(CH₃)CH(CH₃)₂, CH₂N⁺(CH₃)CH₂CH₂CH₃and CH₂N⁺(CH₂CH₂CH₃)₂

LE MÉTHYLE₃HEPTANE CH₃ ‐ CH₂ ‐ CH ‐ CH₂ ‐ CH₂ ‐ CH₂ ‐ CH₃ | CH₃ (on MÉTHYL ‐ ÉTHYL ‐ BUTYLMÉTHANE)

Crystal structure of 4,5,6-tris(dimethylamino)-1,2,3-triazine,(N₃C₃)N(CH₃)₂(CH₃)₂N(CH₃)₂N(CH₃)₂

Alkylsulfonylhydroxylamine CH₃(CH₂)_nSO₂NH0H (n = 1, 2, 3) / Alkylsulfonyl Hydroxylamines CH₃(CH₂)_nSO₂NH0H ( » = 1. 2. 3)