Crystal Structures of CH2 = CHCH2OC(O)CH2CH2SnCl3.OPPh3 and BuOC(O)CH(CH3)CH2SnCl3.OPPh3

Marcel Gielen; Huade Pan; Edward R. T. Tiekink

doi:10.1002/bscb.19931020703

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Crystal Structures of CH₂ = CHCH₂OC(O)CH₂CH₂SnCl₃.OPPh₃ and BuOC(O)CH(CH₃)CH₂SnCl₃.OPPh₃

Marcel Gielen Huade Pan Edward R. T. Tiekink

Year: 1993 Journal: Bulletin des Sociétés Chimiques Belges Vol: 102 (7)Pages: 447-453 Publisher: Wiley

DOI: 10.1002/bscb.19931020703

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Abstract

Abstract The crystal structures of the title compounds, CH 2 CHCH 2 OC(O)CH 2 CH 2 SnCl 3 .OPPh 3 1 and BuOC(O)CH(CH 3 )CH 2 SnCl 3 .OPPh 3 2 , have been determined. The Sn atom in each structure exists in a distorted octahedral geometry defined by three CI atoms, the C and O atoms of a chelating alkoxycarbonylalkyl group and an O atom derived from the strongly attached OPPh 3 ligand.

Keywords:

Octahedron Crystal structure Atom (system on chip) Crystallography Ligand (biochemistry) Crystal (programming language) Chemistry Stereochemistry X-ray crystallography Physics Diffraction

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Organometallic Compounds Synthesis and Characterization

Physical Sciences → Chemistry → Organic Chemistry

Crystal structures of chemical compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Crystallography and molecular interactions

Physical Sciences → Chemistry → Physical and Theoretical Chemistry

Crystal Structures of CH₂ = CHCH₂OC(O)CH₂CH₂SnCl₃.OPPh₃ and BuOC(O)CH(CH₃)CH₂SnCl₃.OPPh₃

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