Synthesis and Reactivity of Fluoro Complexes. Part 1. Cyclooctadiene Rhodium(I) Complexes

José Vicente; Juan Gil‐Rubio; Delia Bautista

doi:10.1021/ic015526e

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Synthesis and Reactivity of Fluoro Complexes. Part 1. Cyclooctadiene Rhodium(I) Complexes

José Vicente Juan Gil‐Rubio Delia Bautista

Year: 2001 Journal: Inorganic Chemistry Vol: 40 (12)Pages: 2636-2637 Publisher: American Chemical Society

DOI: 10.1021/ic015526e

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Abstract

The synthesis of [RhF(COD)]n and its triphenylphosphine adduct 2, and a preliminary study of the reactivity of 2 are reported. The reactivity of the Rh−F bond is illustrated by the reactions that lead to compounds 5 and 6. Compound 5 is the first trifluoromethyl Rh(I) complex characterized by monocrystal X-ray diffraction. Both compounds 2 and 6 are initiators of the polymerization of phenylacetylene.

Keywords:

Chemistry Reactivity (psychology) Phenylacetylene Rhodium Triphenylphosphine Adduct Trifluoromethyl 1,5-Cyclooctadiene Cyclooctadiene Medicinal chemistry Polymerization Polymer chemistry Photochemistry Organic chemistry Catalysis

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Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Fluorine in Organic Chemistry

Life Sciences → Pharmacology, Toxicology and Pharmaceutics → Pharmaceutical Science

Cancer Treatment and Pharmacology

Health Sciences → Medicine → Oncology

Synthesis and Reactivity of Fluoro Complexes. Part 1. Cyclooctadiene Rhodium(I) Complexes

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