JOURNAL ARTICLE
Copolymers of N‐vinyl‐2‐pyrrolidone and 2‐(dimethylamino)ethyl methacrylate, 1. Synthesis, characterization, quaternization
Karine DeboudtMichèle DelporteClaude Loucheux
Year: 1995 Journal: Macromolecular Chemistry and Physics Vol: 196 (1)Pages: 279-290 Publisher: Wiley
Abstract
Abstract 2‐(Dimethylamino)ethyl methacrylate (DMAEM) — N ‐vinyl‐2‐pyrrolidone (VP) copolymers were synthesized and characterized. The copolymerization parameters were determined: r VP = 0,61, r DMAEM = 11,41. The tacticity of DMAEM sequences and the distribution of monomer units were estimated. Then, the experimental conditions for the quaternization of the copolymers with alkyl bromides were defined. The modified copolymers were characterized and the mechanism of the quaternization reaction was studied via potentiometry.
Keywords:
Polymer chemistry 2-Pyrrolidone Copolymer Methacrylate Chemistry Characterization (materials science) Organic chemistry Materials science Polymer Nanotechnology
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22
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0.65
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Citation History
Topics
Advanced Polymer Synthesis and Characterization
Physical Sciences → Chemistry → Organic Chemistry
Inorganic and Organometallic Chemistry
Physical Sciences → Chemistry → Organic Chemistry
Phosphorus compounds and reactions
Physical Sciences → Chemistry → Organic Chemistry
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