An Exafs Study on Carbon‐Supported Mo and Co‐Mo Sulfide Hydrodesulfurization Catalysts

Abstract

Abstract The structure and dispersion of the active phase present in sulfided Mo/C and Co‐Mo/C catalysts are studied by means of Mo K‐edge EXAFS. EXAFS measurements were carried out at liquid N 2 temperature on freshly sulfided catalysts in situ. Due to a high signal‐to‐noise ratio of the experimental data, detailed information about the structural parameters of the active phase can be obtained. The Mo/C and Co‐Mo/C catalysts consist of very small MoS 2 ‐like particles, which contain on average 5 to 6 Mo ions (Mo/C), and 7 to 8 Mo ions (Co‐Mo/C). There are indications for the presence of a Mo‐C interaction in Mo/C and Co‐Mo/C. The Mo‐C coordination distance is estimated to be 1.9 ± 0.1 Å. There are also indications for the presence of a Mo‐Co interaction. The Mo‐Co coordination distance was estimated to be 2.8 ± 0.1 Å.