[(η5‐C5Me4Et)Rh(μ,η2‐P2)2Rh(η5‐C5Me4Et)], a Sandwich Complex with a P4 Rectangle

Otto J. Scherer; Magdalena Swarowsky; Gotthelf Wolmershäuser

doi:10.1002/anie.198804051

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[(η⁵‐C₅Me₄Et)Rh(μ,η²‐P₂)₂Rh(η⁵‐C₅Me₄Et)], a Sandwich Complex with a P₄ Rectangle

Otto J. Scherer Magdalena Swarowsky Gotthelf Wolmershäuser

Year: 1988 Journal: Angewandte Chemie International Edition in English Vol: 27 (3)Pages: 405-406

DOI: 10.1002/anie.198804051

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Abstract

Does cyclo-P4 exist as complex ligand? A partial answer to this question is provided by the structural elucidation of the title compound 1, which was synthesized by cothermolysis of [(C5Me4Et)Rh(CO)2] and white phosphorus (P4). The four P atoms in 1 form a (P2)2 rectangle arranged parallel to the two five-membered rings (Rh: hatched; P: black).

Keywords:

Rhodium Crystallography Ligand (biochemistry) Chemistry Physics Stereochemistry Catalysis

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Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Synthesis and characterization of novel inorganic/organometallic compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Coordination Chemistry and Organometallics

Physical Sciences → Chemistry → Organic Chemistry

[(η⁵‐C₅Me₄Et)Rh(μ,η²‐P₂)₂Rh(η⁵‐C₅Me₄Et)], a Sandwich Complex with a P₄ Rectangle

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[(η5‐C5Me4Et)Rh(μ,η2‐P2)2Rh(η5‐C5Me4Et)], a Sandwich Complex with a P4 Rectangle

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