Azide-bridged Cd(<scp>ii</scp>) 1D coordination polymer with Cd<sub>13</sub>nano-crown-like cluster

Shi‐Qiang Bai; Chen‐Jie Fang; Zheng He; En‐Qing Gao; Chun‐Hua Yan; T. S. Andy Hor

doi:10.1039/c2ce26525g

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Azide-bridged Cd(ii) 1D coordination polymer with Cd₁₃nano-crown-like cluster

Shi‐Qiang Bai Chen‐Jie Fang Zheng He En‐Qing Gao Chun‐Hua Yan T. S. Andy Hor

Year: 2012 Journal: CrystEngComm Vol: 15 (4)Pages: 650-653 Publisher: Royal Society of Chemistry

DOI: 10.1039/c2ce26525g

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Abstract

A novel polymeric one-dimensional 2-acetylpyridine-supported cadmium(ii)-azide shows tridecanuclear Cd13 crown-like clusters with defective supercubane cores, in which the azide ligands show μ-1,1- and μ-1,1,1-N3 bridging modes. © 2013 The Royal Society of Chemistry.

Keywords:

Azide Cluster (spacecraft) Nano- Coordination polymer Chemistry Crown (dentistry) Polymer Crystallography Stereochemistry Materials science Crystal structure Organic chemistry Computer science Composite material Operating system

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Metal-Organic Frameworks: Synthesis and Applications

Physical Sciences → Chemistry → Inorganic Chemistry

Magnetism in coordination complexes

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Nanocluster Synthesis and Applications

Physical Sciences → Materials Science → Materials Chemistry

Azide-bridged Cd(ii) 1D coordination polymer with Cd₁₃nano-crown-like cluster

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