Effective Pyroelectric Coefficient and Polarization Offset of Compositionally Step-like Graded Ferroelectric Structures

Abstract

In this paper, the effective pyroelectric coefficient and polarization offset of the compositionally step-like graded multilayer ferroelectric structures have been studied by use of the first-principles approach. It is exhibited that the dielectric gradient has a nontrivial influence on the effective pyroelectric coefficient, but has a little influence on the polarization offset; and the polarization gradient plays an important role in the abnormal hysteresis loop phenomenon of the compositionally step-like graded ferroelectric structures. Moreover, the origin of the polarization offset is explored, which can be attributed to the polarization gradient in the compositionally step-like graded structure.