(η5‐Pentamethylcyclopentadienyl)iron Complexes with η5‐2,3,5‐Tricarbahexaboranyl and η5‐2,3‐Dihydro‐1,3‐diborolyl Ligands

Walter Siebert; Ralph Hettrich; Hans Pritzkow

doi:10.1002/anie.199402031

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(η⁵‐Pentamethylcyclopentadienyl)iron Complexes with η⁵‐2,3,5‐Tricarbahexaboranyl and η⁵‐2,3‐Dihydro‐1,3‐diborolyl Ligands

Walter Siebert Ralph Hettrich Hans Pritzkow

Year: 1994 Journal: Angewandte Chemie International Edition in English Vol: 33 (2)Pages: 203-204

DOI: 10.1002/anie.199402031

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Abstract

The extreme folding of the heterocycle and the Me groups on the C5 ring stabilize complex 1 to such an extent that an additional C5Me5Fe fragment cannot be stacked to give a triple-decker complex. The green, air-sensitive compound is the first structurally characterized iron sandwich complex with 16 valence electrons.

Keywords:

Valence (chemistry) Chemistry Electron Crystallography Ring (chemistry) Folding (DSP implementation) Stereochemistry Physics Nuclear physics Organic chemistry

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Organoboron and organosilicon chemistry

Physical Sciences → Chemistry → Organic Chemistry

Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Ferrocene Chemistry and Applications

Physical Sciences → Chemistry → Organic Chemistry

(η⁵‐Pentamethylcyclopentadienyl)iron Complexes with η⁵‐2,3,5‐Tricarbahexaboranyl and η⁵‐2,3‐Dihydro‐1,3‐diborolyl Ligands

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