Absolute optical absorption coefficient measurements using transverse photothermal deflection spectroscopy

Abstract

Information about the optical absorption coefficient of solid materials in contact with a fluid phase can be obtained from photothermal deflection (PDS) measurements using both the signal amplitude and phase channels of the PDS response of a system to an optical excitation. This paper presents a theoretical model of photothermal processes in the transverse (TPDS) experimental configuration. The theory is used to determine the dependence of both signal channels on the optical absorption coefficient of the solid material and to define absorption coefficient ranges within which TPDS can be used as a spectroscopic technique. A method concerning the use of the combined amplitude and phase data for the absolute measurement of the absorption coefficient is presented for the experimentally important thermally thick limit.