Electrochemical synthesis and a redetermination of Ni(acac)2(H2O)2·H2O

Xingfu Zhou; Ai-Jie Han; Chu Dao-bao; Zi-Xiang Huang

doi:10.1107/s1600536801016208

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Electrochemical synthesis and a redetermination of Ni(acac)₂(H₂O)₂·H₂O

Xingfu Zhou Ai-Jie Han Chu Dao-bao Zi-Xiang Huang

Year: 2001 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 57 (11)Pages: m506-m508 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536801016208

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Abstract

The title complex, bis(acetylacetonato)diaquanickel(II) monohydrate, [Ni(C5H7O2)2(H2O)2)]·H2O, was easily synthesized in high yield by electrochemical dissolution of nickel metal in an acetylacetone and ethanol solution via direct hydrolysis of the electrolyte solution at a temperature of 333 K. The crystal structure shows octahedral coordination of nickel with two trans aqua ligands. An uncoordinated water molecule engages in hydrogen bonding.

Keywords:

Nickel Electrochemistry Chemistry Dissolution Octahedron Electrolyte Crystal structure Acetone Yield (engineering) Metal Inorganic chemistry Crystallography Materials science Physical chemistry Metallurgy Electrode Organic chemistry

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Magnetism in coordination complexes

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Metal complexes synthesis and properties

Health Sciences → Medicine → Oncology

Metal-Catalyzed Oxygenation Mechanisms

Physical Sciences → Chemistry → Inorganic Chemistry

Electrochemical synthesis and a redetermination of Ni(acac)₂(H₂O)₂·H₂O

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