Inorganic Frameworks from Selenidotetrelate Anions [T2Se6]4− (T = Ge, Sn): Synthesis, Structures, and Ionic Conductivity of [K2(H2O)3][MnGe4Se10] and (NMe4)2[MSn4Se10] (M = Mn, Fe)
Sima HaddadpourMaike MelullisH. StaescheC.R. MariappanBernhard RolingRodolphe CléracStefanie Dehnen
Abstract
Syntheses, structures, and physical properties of three inorganic framework compounds [K(2)(H(2)O)(3)][MnGe(4)Se(10)] (1), (NMe(4))(2)[MnSn(4)Se(10)] (2), and (NMe(4))(2)[FeSn(4)Se(10)] (3) are presented. The title compounds are based on a prominent open framework anionic structure; in these cases, however, they contain K(+), the smallest type of counterion to be included so far (1), or represent Sn analogues (2, 3). Both changes with respect to related compounds are reflected in peculiar physical properties, such as ion conductivity or relatively small band gaps.
Metrics
Citation History
Topics
Related Documents
Different Chemical Environments of [Ge4Se10]4– in the Li+ Compounds [Li4(H2O)16][Ge4Se10]·4.33H2O, [{Li4(thf)12}Ge4Se10], and [Li2(H2O)8][MnGe4Se10], and Ionic Conductivity of Underlying “Li4Ge4Se10”
Marc DuchardtSima HaddadpourThomas KaibPhilipp BronBernhard RolingStefanie Dehnen
Water Encapsulated [(Fe4Se4)Se4]6– Clusters in [Na6(H2O)18][Fe4Se8]
Ursula PachmayrBettina RendenbachNadine LammerSirko KamusellaH.‐H. KlaußS. HolensteinH. LuetkensDirk Johrendt
Electrochemical Synthesis of [NEt4]2[enH]2[Ge2Se6] and [NEt4]4[Sn4Se10]
Chang-Woo ParkMichael A. PellJames A. Ibers
Die Kristallstrukturen von (NEt4 +)2[Se5 2- · 1/2 Se6·Se7] und von (NPr4)2Se11 / The Crystal Structures of (NEt4 +)2[Se5 2- · 1/2 Se6 · Se7] and (NPr4)2Se11
J. DietzUlrich MüllerVolker MüllerKurt Dehnicke
The Mixed Polychalcogenorhenate(IV) Anions [Re4Q4(S3)4(S4)2]4- (Q = Se, Te): Syntheses and Crystal Structures of [NMe4]5[Me2NH2]3[Re4Se4(S3)4(S4)2]2·2.25H2O and [NH4]4[Re4Te4(S3)4(S4)2]·8H2O
Yuri V. MironovMichael A. PellThomas E. Albrecht‐SchmittJames A. Ibers