Mechanism of H2-promoted oxidation of nitrogen monoxide over Ag/Al2O3

N. A. Sadokhina; V. I. Bukhtiyarov; Alina I. Mytareva; Ren I. Kvon; Andrey V. Bukhtiyarov; A. Yu. Stakheev

doi:10.1016/j.mencom.2011.09.015

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Mechanism of H2-promoted oxidation of nitrogen monoxide over Ag/Al2O3

N. A. Sadokhina V. I. Bukhtiyarov Alina I. Mytareva Ren I. Kvon Andrey V. Bukhtiyarov A. Yu. Stakheev

Year: 2011 Journal: Mendeleev Communications Vol: 21 (5)Pages: 274-276 Publisher: Elsevier BV

DOI: 10.1016/j.mencom.2011.09.015

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Abstract

H2-promoted oxidation of NO to NO2 over Ag/Al2O3 proceeds via two-step mechanism: (1) formation of surface nitrate species, and (2) reduction of this species with NO. Hydrogen plays a crucial role at the first step.

Keywords:

Chemistry Carbon monoxide Mechanism (biology) Nitrogen Hydrogen Nitrate Photochemistry Monoxide Inorganic chemistry Catalysis Organic chemistry

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Catalytic Processes in Materials Science

Physical Sciences → Materials Science → Materials Chemistry

Advanced Photocatalysis Techniques

Physical Sciences → Energy → Renewable Energy, Sustainability and the Environment

Ammonia Synthesis and Nitrogen Reduction

Physical Sciences → Chemical Engineering → Catalysis

Mechanism of H2-promoted oxidation of nitrogen monoxide over Ag/Al2O3

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