JOURNAL ARTICLE
Synthesis, characterization, and catalytic properties of some new ruthenium(II)/(III) complexes containing N,N-donor ligands
Year: 2007 Journal: Journal of Coordination Chemistry Vol: 60 (12)Pages: 1279-1289 Publisher: Taylor & Francis
Abstract
This article describes the preparation and characterization of cis-[Ru(bipy)2L](ClO4)2 and trans-[RuCl2L2] · Cl (bipy = 2,2′-bipyridyl and L = ortho-phenylenediamine (o-phd), 2-aminopyridine (2-apy) and 2-aminobenzonitrile (2-abn), and examines the catalytic oxidations of benzyl alcohol, benzohydrol and pipronyl alcohol by cis-[Ru(bipy)2 (o-phd)](ClO4)2 and trans-[RuCl2(o-phd)2] · Cl complexes at room temperature and in the presence of N-methyl morpholine-N-oxide (NMO) as co-oxidant.
Keywords:
Chemistry Ruthenium Catalysis Morpholine Medicinal chemistry Benzyl alcohol Alcohol Stereochemistry Polymer chemistry Organic chemistry
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8
Cited By
0.17
FWCI (Field Weighted Citation Impact)
20
Refs
0.53
Citation Normalized Percentile
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Citation History
Topics
Metal complexes synthesis and properties
Health Sciences → Medicine → Oncology
Inorganic and Organometallic Chemistry
Physical Sciences → Chemistry → Organic Chemistry
Magnetism in coordination complexes
Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials
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