Asymmetric hysteresis loops and its dependence on magnetic anisotropy in exchange biased Co/CoO core-shell nanoparticles

Abstract

The origin of asymmetry in field cooled (FC) hysteresis loops exhibiting exchange bias (EB) is investigated by studying the static and dynamic magnetic properties of core-shell Co/CoO nanoparticles. Two distinct freezing temperatures coresponding to the core (Tf-cr ∼ 190 K) and the shell moments (Tf-sh ∼ 95 K) are obtained from the energy barrier distribution. The FC loops are symmetric in the temperature range Tf-sh ≤ T ≤ Tf-cr, however, asymmetry in hysteresis is observed immediately below Tf-sh. These intriguing features are also probed by radio frequency transverse susceptibility (TS) experiments. We show that the first anisotropy fields obtained from the demagnetization and return curves of field cooled TS measurement, shift along the negative field axis and strikingly resemble the temperature dependence of EB. Field cooled TS measurements reveal the effect of competing Zeeman and anisotropy energy above and below Tf-sh to account for the development of asymmetry. Our study indicates that asymmetry in FC hysteresis loops is intrinsic to core-shell nanoparticles and develops only below the freezing temperature of the shell due to enhanced magnetic anisotropy.