JOURNAL ARTICLE

Structure of (2,2'-bipyridine-3,3'-dicarboxylic acid)dichlorocopper(II) monohydrate

Richard GoddardB. HemalathaM.V. Rajasekharan

Year: 1990 Journal:   Acta Crystallographica Section C Crystal Structure Communications Vol: 46 (1)Pages: 33-35   Publisher: Wiley

Abstract

[CuCl 2 (C 12 H 8 N 2 O 4 )]•H 2 O cristallise dans Pbca avec a=9,932, b=17,560 et c=17,065 A, Z=8; affinement jusqu'a R=0,034. Coordination approximativement plan carre autour de Cu. Presence d'une interaction additionnelle faible entre l'atome Cu et l'atome Cl et les O carbonyl de l'acide carboxylique conduisant a un arrangement approximativement octaedrique autour de l'atome metallique. Les groupes acide carboxylique ou coordines et les molecules d'eau forment un reseau de liaisons hydrogene intermoleculaires

Keywords:
Chemistry Molecule Stereochemistry Crystallography X-ray crystallography Physics Diffraction Organic chemistry

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Citation History

Topics

Metal complexes synthesis and properties
Health Sciences →  Medicine →  Oncology
Crystal structures of chemical compounds
Physical Sciences →  Chemistry →  Inorganic Chemistry
Magnetism in coordination complexes
Physical Sciences →  Materials Science →  Electronic, Optical and Magnetic Materials

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