Single‐crystal Raman studies on Sr(ClO3)2 and BrO3− and IO3− ions matrix isolated in Sr(ClO3)2
H. D. LutzE. AliciTh. Kellersohn
Abstract
Abstract Single‐crystal Raman spectra of Sr(ClO 3 ) 2 and Sr(ClO 3 ) 2 crystals with matrix isolated BrO 3 − and IO 3 − guest ions are presented and discussed in terms of TO/LO splitting and distortion of the XO 3 − ions. Because of the large distortion of these ions in the structure (site symmetry C 1 ), no intra‐ionic vibrational coupling of the XO vibrations to symmetric (ν 1 ) and asymmetric (ν 3 ) stretching modes occurs. This is proved by oriented gas model calculations of the intensities of the guest ion Raman bands. The infrared and Raman spectra of polycrystalline samples of the isostructural compounds Ba(ClO 3 ) 2 , Ba(BrO 3 ) 2 II, Pb(ClO 3 ) 2 and Pb(BrO 3 ) 2 are also reported.
Metrics
Citation History
Topics
Related Documents
Unusual ion UO4− formed upon collision induced dissociation of [UO2(NO3)3]−, [UO2(ClO4)3]−, [UO2(CH3COO)3]− ions
Marzena SokalskaMałgorzata PrussakowskaMarcin HoffmannBłażej GierczykRafał Frański
The crystal structures of the cryptates Ag(C222)X, X = ClO4 −, NO3 −, ClO3 −, BrO3 −, IO4 −, ReO4 −, BF4 −, PF6 −, AsF6 −, and Na(C222)X, X = ClO4 −, IO4 −, ReO4 −
Substitution of IO3 −, IO4 −, SeO3 2−, and SeO4 2− for CO3 2− in Na4[UO2(CO3)3]
Shijun WuF. ChenAntonio SimonettiThomas E. Albrecht‐Schmitt
A comparative study of the crystal structures of Ba(ClO3)2, Ba(BrO3)2 II, Pb(ClO3)2, and Sr(ClO3)2
H. D. LutzW. BuchmeierM. JungT. Kellersohn
A comparative study of the crystal structures of Ba(ClO3)2, Ba(BrO3)2II, Pb(ClO3)2, and Sr(ClO3)2
H. D. LutzW. BuchmeierM. JungTh. Kellersohn