A New Magnetically Ordered Polymorph of CuMoO<sub>4</sub>: Synthesis and Characterization of ε-CuMoO<sub>4</sub>

Jaewook Baek; Athena S. Sefat; David Mandrus; P. Shiv Halasyamani

doi:10.1021/cm801162j

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A New Magnetically Ordered Polymorph of CuMoO₄: Synthesis and Characterization of ε-CuMoO₄

Jaewook Baek Athena S. Sefat David Mandrus P. Shiv Halasyamani

Year: 2008 Journal: Chemistry of Materials Vol: 20 (12)Pages: 3785-3787 Publisher: American Chemical Society

DOI: 10.1021/cm801162j

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Abstract

A new polymorph of CuMoO4, ε-CuMoO4, has been synthesized and characterized. The material exhibits a three-dimensional structure with tetramers of edge-shared Cu2+O5 square pyramids that link to the Mo6+O4 tetrahedra. Magnetic susceptibility measurements indicate that the material orders magnetically, with a ferromagnetic component below 10 K.

Keywords:

Tetrahedron Magnetic susceptibility Characterization (materials science) Ferromagnetism Crystallography Materials science Enhanced Data Rates for GSM Evolution Component (thermodynamics) Square (algebra) Condensed matter physics Chemistry Nanotechnology Physics Mathematics Geometry Thermodynamics

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Topics

Advanced Condensed Matter Physics

Physical Sciences → Physics and Astronomy → Condensed Matter Physics

Magnetic and transport properties of perovskites and related materials

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Crystal Structures and Properties