Homoepitaxial Single-Crystal Boron-Doped Diamond Electrodes for Electroanalysis

Abstract

In order to study the properties of single-crystal boron-doped diamond electrodes for electroanalysis, (100) and (111) boron-doped homoepitaxial single-crystal and polycrystalline diamond thin films were deposited by means of microwave plasma-assisted chemical vapor deposition. Features in the cyclic voltammograms (CVs) for aqueous supporting electrolyte and in aqueous for polycrystalline electrodes were dominated by behavior typical of (111) single-crystal facets, rather than (100) facets. Apparent heterogeneous electron-transfer rate constants for various redox systems were estimated with CV simulation at polycrystalline, (111) and (100, off-axis, 4°). Based on comparison with the Marcus model, the behavior of the values, except for that of indicates apparent outer-sphere electron-transfer, but with a lower density of states compared to glassy carbon or typical metal electrodes. The (111) homoepitaxial film performed better than a polycrystalline film in the cyclic voltammetric detection of serotonin, with signal-to-background ratios of 5 and 2, respectively. Single-crystal diamond may thus be an even more optimal electrode material for electroanalysis than polycrystalline diamond, which has been shown to have superior characteristics as an electrode material. © 2002 The Electrochemical Society. All rights reserved.