Conventional and inverse magnetocaloric effects in La0.45Sr0.55MnO3 nanoparticles

Abstract

The magnetocaloric effect of La0.45Sr0.55MnO3 nanoparticles was studied by dc magnetization measurements. A sample with mean particle size of about 140 nm exhibits both a conventional magnetocaloric effect around the Curie temperature (≈ 295 K) and a large inverse magnetocaloric effect around the antiferromagnetic-ferromagnetic transition temperature (≈ 200 K). The change of magnetic entropy increases monotonically with applied magnetic field and reaches the values of 5.51 J/kg K and − 2.35 J/kg K at 200 K and 295 K, respectively, in an applied field of 5 T. The antiferromagnetic-ferromagnetic transition is absent in a 36 nm size sample, which shows only a broad ferromagnetic transition around 340 K and a small change in magnetic entropy near room temperature. The results are discussed in terms of the entropy difference between the A-type antiferromagnetic ground state of La0.45Sr0.55MnO3 and the low moment ferromagnetic state. By comparing the results obtained on nanoparticles and bulk La0.45Sr0.55MnO3, one can conclude that the inverse magnetocaloric effect in a material showing the antiferromagnetic-ferromagnetic transition could be improved over a wide range of temperature by tuning the spin disorder in the antiferromagnetic state.