Methine‐selective deuteration of V(acac)3, [Co(acac)2]4, and Al(acac)3

Daniel E. Ryan; Kōji Nakanishi

doi:10.1002/jlcr.2580360611

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Methine‐selective deuteration of V(acac)₃, [Co(acac)₂]₄, and Al(acac)₃

Daniel E. Ryan Kōji Nakanishi

Year: 1995 Journal: Journal of Labelled Compounds and Radiopharmaceuticals Vol: 36 (6)Pages: 595-598 Publisher: Wiley

DOI: 10.1002/jlcr.2580360611

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Abstract

Abstract In solid state NMR studies of transition metal acetylacetonate complexes, peak assignments required complexes deuterated at methine or methyl positions. The preparation of methine‐deuterated complexes—V(acac‐3‐ 2 H) 3 , [Co(acac‐3‐ 2 H) 2 ] 4 , and Al(acac‐3‐ 2 H) 3 —is presented. This method is applicable to preparations of methyl‐deuterated complexes as well.

Keywords:

Chemistry Deuterium Acetylacetone Transition metal Diketone Kinetic isotope effect Inorganic chemistry Medicinal chemistry Physical chemistry Nuclear chemistry Organic chemistry Catalysis

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Advanced NMR Techniques and Applications

Physical Sciences → Chemistry → Spectroscopy

Advanced Chemical Physics Studies

Physical Sciences → Physics and Astronomy → Atomic and Molecular Physics, and Optics

Crystallography and molecular interactions

Physical Sciences → Chemistry → Physical and Theoretical Chemistry

Methine‐selective deuteration of V(acac)₃, [Co(acac)₂]₄, and Al(acac)₃

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