Cs2SnTe4, ein Polytelluridostannat(IV) mit Kettenstruktur 1 ∞[SnTe2- 4] / Cs2SnTe4, a Polytelluridostannate(IV ) with Chain Structure 1 ∞[SnTe2- 4]

William S. Sheldrick; B. van der Schaaf

doi:10.1515/znb-1994-0112

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Cs₂SnTe₄, ein Polytelluridostannat(IV) mit Kettenstruktur ¹ _∞[SnTe^2- ₄] / Cs₂SnTe₄, a Polytelluridostannate(IV ) with Chain Structure ¹ _∞[SnTe^2- ₄]

William S. Sheldrick B. van der Schaaf

Year: 1994 Journal: Zeitschrift für Naturforschung B Vol: 49 (1)Pages: 57-59 Publisher: De Gruyter

DOI: 10.1515/znb-1994-0112

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Abstract

Abstract The cesium polytelluridostannate(IV) Cs 2 SnTe 4 has been prepared by methanolothermal reaction of Cs 2 CO 3 with Sn and Te at 190 °C. The crystal structure contains chain anions 1 ∞ [SnTe 2- 4 ] in which individual SnTe 4 tetrahedra are linked via Te -Te bonds of length 2.814(3) Å. Weak Te∙∙∙Te secondary bonds of length 3.631(3)-3.663(3) Å connect neighbouring chains into a framework structure. Nine Te atoms from three chain anions participate in the coordination sphere of the cesium cation.

Keywords:

Crystallography Caesium Crystal structure Chemistry Tetrahedron Bond length Materials science Inorganic chemistry

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Crystal Structures and Properties

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Organometallic Compounds Synthesis and Characterization

Physical Sciences → Chemistry → Organic Chemistry

Solid-state spectroscopy and crystallography

Physical Sciences → Materials Science → Materials Chemistry

Cs₂SnTe₄, ein Polytelluridostannat(IV) mit Kettenstruktur ¹ _∞[SnTe^2- ₄] / Cs₂SnTe₄, a Polytelluridostannate(IV ) with Chain Structure ¹ _∞[SnTe^2- ₄]

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