Zur Thermodynamik der Metallcarbonate 3. Mitteilung [1]. Löslichkeitskonstanten und Freie Bildungsenthalpien von ZnCO3 und Zn5(OH)6(CO3)2 bei 25°

P. Schindler; Michael Reinert; Heinz Gamsjäger

doi:10.1002/hlca.19690520814

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Zur Thermodynamik der Metallcarbonate 3. Mitteilung [1]. Löslichkeitskonstanten und Freie Bildungsenthalpien von ZnCO₃ und Zn₅(OH)₆(CO₃)₂ bei 25°

P. Schindler Michael Reinert Heinz Gamsjäger

Year: 1969 Journal: Helvetica Chimica Acta Vol: 52 (8)Pages: 2327-2332 Publisher: Wiley

DOI: 10.1002/hlca.19690520814

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Abstract

Abstract The solubilities of ZnCO 3 and Zn 5 (OH) 6 (CO 3 ) 2 have been investigated at 25°C in solutions of the constant ionic strength 0,2 M consisting primarily of sodium perchlorate. From experimental data the following values for equilibrium constants and G IBBS free energies of formation are deduced: A predominance area diagram for the ternary system Zn 2+ –H 2 O–CO 2( g ) including ZnO, ZnCO 3 , Zn 5 (OH) 6 (CO 3)2 , and Zn 2+ is given.

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Chemistry Ternary operation Physical chemistry Zinc Crystallography

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Chemical and Physical Properties in Aqueous Solutions

Physical Sciences → Chemical Engineering → Filtration and Separation

Thermal and Kinetic Analysis

Physical Sciences → Materials Science → Materials Chemistry

Crystallization and Solubility Studies

Physical Sciences → Materials Science → Materials Chemistry

Zur Thermodynamik der Metallcarbonate 3. Mitteilung [1]. Löslichkeitskonstanten und Freie Bildungsenthalpien von ZnCO₃ und Zn₅(OH)₆(CO₃)₂ bei 25°

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