JOURNAL ARTICLE
A New Approach to Osmium-Catalyzed Asymmetric Dihydroxylation and Aminohydroxylation of Olefins
Malin AnderssonRobert EppleValery V. FokinK. Barry Sharpless
Year: 2002 Journal: Angewandte Chemie International Edition Vol: 41 (3)Pages: 472-475 Publisher: Wiley
Abstract
Simple hydroxyamino acid derivatives act as chiral ligands in osmium-catalyzed dihydroxylation and aminohydroxylation of olefins (see scheme). These are the first examples of asymmetric osmium-catalyzed processes proceeding in the second catalytic cycle with resident ligands on the metal center.
Keywords:
Dihydroxylation Osmium Catalysis Catalytic cycle Chemistry Hydroxylation Enantioselective synthesis Combinatorial chemistry Organic chemistry Ruthenium Enzyme
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15
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0.99
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Citation History
Topics
Synthesis and Catalytic Reactions
Physical Sciences → Chemistry → Organic Chemistry
Asymmetric Synthesis and Catalysis
Physical Sciences → Chemistry → Organic Chemistry
Asymmetric Hydrogenation and Catalysis
Physical Sciences → Chemistry → Inorganic Chemistry
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