Polymeric (η<sup>5</sup>,μ‐2,3‐Dihydro‐1,3‐diborolyl)nickel—the First Polydecker Sandwich Compound

Thomas Kuhlmann; Siegmar Roth; Jacqués Rozière; Walter Siebert

doi:10.1002/anie.198601051

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Polymeric (η⁵,μ‐2,3‐Dihydro‐1,3‐diborolyl)nickel—the First Polydecker Sandwich Compound

Thomas Kuhlmann Siegmar Roth Jacqués Rozière Walter Siebert

Year: 1986 Journal: Angewandte Chemie International Edition in English Vol: 25 (1)Pages: 105-107

DOI: 10.1002/anie.198601051

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Abstract

An old idea in sandwich chemistry has now been realized: The black, film-like polymer 2 was obtained by thermal polycondensation of the dinickel complex 1 in vacuo. The thermally very stable but oxygen-sensitive 2 is a semiconductor. EXAFS investigations suggest a distorted polydecker sandwich structure.

Keywords:

Nickel Polymer Extended X-ray absorption fine structure Condensation polymer Materials science Polymer chemistry Chemistry Crystallography Metallurgy Composite material Physics Optics Absorption spectroscopy

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Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Organoboron and organosilicon chemistry

Physical Sciences → Chemistry → Organic Chemistry

Synthesis and characterization of novel inorganic/organometallic compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Polymeric (η⁵,μ‐2,3‐Dihydro‐1,3‐diborolyl)nickel—the First Polydecker Sandwich Compound

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