The I42+cation. X-Ray crystal structures of (I42+)(AsF6–)2and (I42+)(Sb3F14–)(SbF6–)

R. J. Gillespie; R. C. Kapoor; R. Faggiani; C. J. L. Lock; Michael P. Murchie; Jack Passmore

doi:10.1039/c39830000008

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The I₄²⁺cation. X-Ray crystal structures of (I₄²⁺)(AsF₆^–)₂and (I₄²⁺)(Sb₃F₁₄^–)(SbF₆^–)

R. J. Gillespie R. C. Kapoor R. Faggiani C. J. L. Lock Michael P. Murchie Jack Passmore

Year: 1983 Journal: Journal of the Chemical Society Chemical Communications Pages: 8-9 Publisher: Royal Society of Chemistry

DOI: 10.1039/c39830000008

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Abstract

The I42+ cation has been fully characterised for the first time by the preparation of the compounds (I42+)(AsF6–)2 and (I42+)(Sb3F14–)(SbF6–) and the determination of their structures by X-ray crystallography; the I42+ cation has a rectangular structure and may be considered to consist of two I2+ cations held together by two rather weak bonds.

Keywords:

Crystallography Crystal structure X-ray crystallography Chemistry X-ray Physics Diffraction Nuclear physics Optics

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Inorganic Fluorides and Related Compounds

Physical Sciences → Chemistry → Inorganic Chemistry

X-ray Diffraction in Crystallography

Physical Sciences → Materials Science → Materials Chemistry

Luminescence Properties of Advanced Materials

Physical Sciences → Materials Science → Materials Chemistry

The I₄²⁺cation. X-Ray crystal structures of (I₄²⁺)(AsF₆^–)₂and (I₄²⁺)(Sb₃F₁₄^–)(SbF₆^–)

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