Length characterization of DNA-wrapped carbon nanotubes using Raman spectroscopy

Abstract

A systematic resonance Raman study has been carried out on DNA-wrapped single walled carbon nanotubes (SWCNTs) of three different average lengths ⟨Ltube⟩ using seven different values of laser excitation energy Elaser. The dependence of the intensity ratio of the D-band and G-band Raman features (ID∕IG) on ⟨Ltube⟩ indicates that nanotube length can be used as an important structural parameter for Raman characterization. By systematically varying Elaser, the ratio ID∕IG is found to be much stronger for metallic than for semiconducting SWCNTs but appears to have the same functional dependence on Elaser and ⟨Ltube⟩ or crystallite size as does nanographite.