Reduced-temperature ordering of FePt nanoparticle assembled films by Fe₃₀Pt₇₀/Fe₃O₄core/shell structure

Abstract

In this paper, Fe30Pt70/Fe3O4 core/shell nanoparticles were synthesized by chemical routine and the layered polyethylenimine (PEI)-Fe30Pt70/Fe3O4 structure was constructed by molecule-mediated self-assembly technique. The dimension of core/shell structured nanoparticles was that of 4nm core and 2nm shell. After annealing under a flow of forming gas (50%Ar2+30%H2) for 1h at or above 400°C, the iron oxide shell was reduced to Fe and diffused to Pt-rich core, which leaded to the formation of L10 phase FePt at low temperature. The x-ray diffraction results and magnetic properties measurement showed that the chemical ordering temperature of Fe30Pt70/Fe3O4 core/shell nanoparticles assembly can be reduced to as low as 400°C. The sample annealed at 400°C showed the coercivity of 4KOe with the applied field of 1.5T. The core/shell structure was suggested to be an effective way to reduce the ordering temperature obviously.