Crystal structure of a novel mixed valence MoV–MoVIheteropolymolybdate cluster: [H3O+]6[Mo57V6O183(NO)6(H2O)18]6–·89H2O

Shiwei Zhang; Guiqing Huang; Mei‐Cheng Shao; Tang Youqi

doi:10.1039/c39930000037

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Crystal structure of a novel mixed valence Mo^V–Mo^VIheteropolymolybdate cluster: [H₃O⁺]₆[Mo₅₇V₆O₁₈₃(NO)₆(H₂O)₁₈]^6–·89H₂O

Shiwei Zhang Guiqing Huang Mei‐Cheng Shao Tang Youqi

Year: 1993 Journal: Journal of the Chemical Society Chemical Communications Vol: 0 (1)Pages: 37-38 Publisher: Royal Society of Chemistry

DOI: 10.1039/c39930000037

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Abstract

Reaction of sodium molybdate (Na2MoO4·2H2O) and ammonium metavanadate (NH4VO3) with hydroxylamine hydrochloride results in the formation of the title compound, which consists of three 19-molybdate subunits being connected by six VO6 octahedra, and six bridging water molecules; both the manner of linking of the VO6 octahedra to the 19-molybdate subunit and the formation of a polymetallate cluster containing 57 discrete Mo atoms, are hitherto unknown features.

Keywords:

Molybdate Ammonium molybdate Octahedron Chemistry Crystallography Ammonium metavanadate Molybdenum Crystal structure Sodium molybdate Cluster (spacecraft) Valence (chemistry) Molecule Ammonium Inorganic chemistry Vanadium Zinc

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Polyoxometalates: Synthesis and Applications

Physical Sciences → Materials Science → Materials Chemistry

Metal-Organic Frameworks: Synthesis and Applications

Physical Sciences → Chemistry → Inorganic Chemistry

Vanadium and Halogenation Chemistry

Physical Sciences → Chemistry → Inorganic Chemistry

Crystal structure of a novel mixed valence Mo^V–Mo^VIheteropolymolybdate cluster: [H₃O⁺]₆[Mo₅₇V₆O₁₈₃(NO)₆(H₂O)₁₈]^6–·89H₂O

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Crystal structure of a novel mixed valence MoV–MoVIheteropolymolybdate cluster: [H3O+]6[Mo57V6O183(NO)6(H2O)18]6–·89H2O

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Crystal structure of a novel mixed valence Mo^V–Mo^VIheteropolymolybdate cluster: [H₃O⁺]₆[Mo₅₇V₆O₁₈₃(NO)₆(H₂O)₁₈]^6–·89H₂O

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Vergleich der heteropolyanionen [PMo₉O₃₁(H₂O)₃]³⁻, [P₂Mo₁₈O₆₂]⁶⁻ und [P₂W₁₈O₆₂]⁶⁻

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(Organoarsonato)polyoxovanadium‐Cluster: Eigenschaften und Strukturen des V^v‐Clusters [V₁₀ O₂₄ (O₃AsC₆H₄‐4‐NH₂)₃]⁴⁻ und des V^IV/V^v‐Clusters [H²{V₆O₁₀(O₃AsC₆H₅)₆}]²⁻

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