Tris(1,10-phenanthroline-κ2N,N′)iron(III) trinitrate monohydrate

M. Odoko; Nobuo Okabe

doi:10.1107/s1600536804027345

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Tris(1,10-phenanthroline-κ²N,N′)iron(III) trinitrate monohydrate

M. Odoko Nobuo Okabe

Year: 2004 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 60 (12)Pages: m1822-m1824 Publisher: International Union of Crystallography

DOI: 10.1107/s1600536804027345

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Abstract

In the title compound, [Fe(C12H8N2)3](NO3)3·H2O, the Fe atom lies on a twofold rotation axis and is coordinated by three planar 1,10-phenanthroline ligands in a slightly distorted octahedral environment. One nitrate anion and the disordered water molecule also lie on twofold rotation axes. The crystal structure is stabilized by partial stacking and hydrogen-bonding interactions.

Keywords:

Phenanthroline Octahedron Stacking Crystallography Chemistry Hydrogen bond Crystal structure Ion Tris Rotation (mathematics) Planar Inorganic chemistry Molecule Geometry Mathematics

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Metal complexes synthesis and properties

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Tris(1,10-phenanthroline-κ²N,N′)iron(III) trinitrate monohydrate

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