Horseradish peroxidase-catalysed oxidation of aromatic tertiary amines with hydrogen peroxide

Guido Galliani; Bruno Rindone; Augusto Marchesini

doi:10.1039/p19780000456

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Horseradish peroxidase-catalysed oxidation of aromatic tertiary amines with hydrogen peroxide

Guido Galliani Bruno Rindone Augusto Marchesini

Year: 1978 Journal: Journal of the Chemical Society Perkin Transactions 1 Pages: 456-456 Publisher: Royal Society of Chemistry

DOI: 10.1039/p19780000456

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Abstract

The horseradish peroxidase-catalysed oxidation of aromatic tertiary amines with hydrogen peroxide leads to a secondary amine and an aldehyde. With alkylmethylanilines demethylation is preferred to dealkylation. Evidence is given for the coexistence of the usual peroxidation reaction and a free radical chain reaction which depends upon oxygen concentration.

Keywords:

Horseradish peroxidase Chemistry Hydrogen peroxide Demethylation Peroxidase Amine gas treating Tertiary amine Aldehyde Alkylation Peroxide Aromatic amine Photochemistry Organic chemistry Catalysis Enzyme Biochemistry

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Click Chemistry and Applications

Physical Sciences → Chemistry → Organic Chemistry

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Life Sciences → Biochemistry, Genetics and Molecular Biology → Molecular Biology

Photochromic and Fluorescence Chemistry

Physical Sciences → Materials Science → Materials Chemistry

Horseradish peroxidase-catalysed oxidation of aromatic tertiary amines with hydrogen peroxide

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