Photodimerizationof (η<sup>5</sup>-cyclopentadienyl)(η<sup>6</sup>-dibenzo-p-quinodimethane)ruthenium(<scp>II</scp>) hexafluorophosphate

Daniel T. Glatzhofer; Yongwu Liang; Masood A. Khan

doi:10.1039/c39930000742

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Photodimerizationof (η⁵-cyclopentadienyl)(η⁶-dibenzo-p-quinodimethane)ruthenium(II) hexafluorophosphate

Daniel T. Glatzhofer Yongwu Liang Masood A. Khan

Year: 1993 Journal: Journal of the Chemical Society Chemical Communications Pages: 742-743 Publisher: Royal Society of Chemistry

DOI: 10.1039/c39930000742

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Abstract

Photodimerization of [(RuCp)(η6-dbqm)]+PF6–3(Cp =η5-cyclopentadienyl; dbqm = dibenzo-p-quinodimethane) in solution using visible light selectively afforded a stable organometallic adduct of the normally labile intramolecular photoisomer of [2.2](9,10)anthracenophane.

Keywords:

Ruthenium Hexafluorophosphate Cyclopentadienyl complex Chemistry Medicinal chemistry Radiochemistry Organic chemistry Catalysis Ionic liquid

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Fluorine in Organic Chemistry

Life Sciences → Pharmacology, Toxicology and Pharmaceutics → Pharmaceutical Science

Chemical Synthesis and Analysis

Life Sciences → Biochemistry, Genetics and Molecular Biology → Molecular Biology

Photochromic and Fluorescence Chemistry

Physical Sciences → Materials Science → Materials Chemistry

Photodimerizationof (η⁵-cyclopentadienyl)(η⁶-dibenzo-p-quinodimethane)ruthenium(II) hexafluorophosphate

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