Biphasic Hydroformylation of 1-Hexene with Carbon Dioxide Catalyzed by Ruthenium Complex in Ionic Liquids

Ken‐ichi Tominaga; Yoshiyuki Sasaki

doi:10.1246/cl.2004.14

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Biphasic Hydroformylation of 1-Hexene with Carbon Dioxide Catalyzed by Ruthenium Complex in Ionic Liquids

Ken‐ichi Tominaga Yoshiyuki Sasaki

Year: 2003 Journal: Chemistry Letters Vol: 33 (1)Pages: 14-15 Publisher: Oxford University Press

DOI: 10.1246/cl.2004.14

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Abstract

Abstract Hydroformylation of 1-hexene using carbon dioxide as carbonyl carbon source attained high yield and good chemoselectivity in heptanols when a ruthenium complex was used in biphasic ionic liquid–toluene system.

Keywords:

Hydroformylation Chemistry 1-Hexene Ruthenium Catalysis Ionic liquid Carbon dioxide Hexene Ionic bonding Organic chemistry Photochemistry Rhodium Ion Ethylene

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Carbon dioxide utilization in catalysis

Physical Sciences → Chemical Engineering → Process Chemistry and Technology

Ionic liquids properties and applications

Physical Sciences → Chemical Engineering → Catalysis

Catalysis and Oxidation Reactions

Physical Sciences → Chemical Engineering → Catalysis

Biphasic Hydroformylation of 1-Hexene with Carbon Dioxide Catalyzed by Ruthenium Complex in Ionic Liquids

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