Schiff Base Formation upon Complexation of Tris(acetylacetonato)iron with N[(CH2CH2NH2)(CH2CH2OH)(CH2CH2CH2OH)]
F. Ekkehardt HahnChristoph J. JocherThomas LüggerTania Pape
Abstract
Abstract The reaction of the unsymmetrical aliphatic tripodal ligand N[(CH 2 CH 2 NH 2 )(CH 2 CH 2 OH)(CH 2 CH 2 CH 2 OH)] (H 4 ‐3 ) with tris(acetylacetonato)iron(III) gives the dinuclear bis(μ‐alkoxo) bridged complex [Fe{N(CH 2 CH 2 N=C(CH 3 )CHC(CH 3 )O)‐ (CH 2 CH 2 CH 2 O)(CH 2 CH 2 O)}] 2 [Fe(η 5 , μ‐ 4 )] 2 ( 5 ). The new ligand 4 3‐ is obtained by reaction of the primary amine function of H 4 ‐3 with one of the acetylacetonato ligands under imine formation. The iron atoms in complex 5 are coordinated in an octahedral fashion within an N 2 O 4 environment. Complex 5 contains three different alkoxo donor groups.
Metrics
Topics
Related Documents
Reactions of Diethylaminodimethylaluminum Dimer with the Tripodal Ligands CH3C(CH2NH2)2(CH2OH) and CH3C(CH2NH2)(CH2OH)(CH2SPh): Crystal Structure of [AlMe2]3Al[CH3C(CH2NH)2(CH2O)]2
Mung-Dar LiChung‐Cheng ChangMichael Y. ChiangShiu-Tzung Liu
CH3CH2OH
Comparison of Three Isoelectronic Multiple-Well Reaction Systems: OH + CH2O, OH + CH2CH2, and OH + CH2NH
Mohamad Akbar AliJohn R. Barker
Unimolecular reactions of isolated organic ions: reactions of the immonium ions CH2N+(CH3)CH(CH3)2, CH2N+(CH3)CH2CH2CH3and CH2N+(CH2CH2CH3)2
Richard D. BowenAlex W. ColburnPeter J. Derrick
Formation of an Iron(III) Oxo Cubane Core Fe4(μ4-O)4 from FeCl3 and the Unsymmetrical Tripodal Ligand N[(CH2CH2NH2)(CH2CH2OH)(CH2CH2CH2OH)]
F. Ekkehardt HahnChristoph J. JocherThomas Lügger