Thermomechanical properties of shape memory polymer subjected to tension in various conditions

Abstract

Thermomechanical and functional properties of shape memory polyurethane are presented. A background of the polymer shape memory effects is described. Elastic modulus at various temperatures and the polyurethane parameters important for the practical applications, called shape fixity and shape recovery, are derived. Taking advantages from the high quality testing machine and infrared camera, mechanical characteristics and temperature changes of the shape memory polyurethane specimens subjected to tension test carried out in various conditions are clarified and analyzed. Stress-strain curves and the relevant temperature changes are recorded both in the elastic and the plastic ranges of deformation. A significant value of a thermoelastic effect is observed. Taking into account the obtained experimental data from the polyurethane tension tests performed at room temperature, followed by the heating above its glass transition temperature, the shape memory polyurethane properties are studied.