Carbonylation of methanol in supercritical CO2 catalysed by a supported rhodium complex

R.J. Sowden; Murielle Sellin; Nicola De Blasio; David J. Cole‐Hamilton

doi:10.1039/a906653e

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Carbonylation of methanol in supercritical CO2 catalysed by a supported rhodium complex

R.J. Sowden Murielle Sellin Nicola De Blasio David J. Cole‐Hamilton

Year: 1999 Journal: Chemical Communications Pages: 2511-2512 Publisher: Royal Society of Chemistry

DOI: 10.1039/a906653e

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Abstract

A rhodium complex supported on polyvinylpyrrolidone catalyses the carbonylation of methanol to methyl ethanoate and ethanoic acid in supercritical CO2 at rates up to ca. 50% those in liquid solution but with minimal catalyst leaching.

Keywords:

Carbonylation Rhodium Methanol Supercritical fluid Chemistry Polyvinylpyrrolidone Catalysis Organic chemistry Leaching (pedology) Carbon monoxide

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Carbon dioxide utilization in catalysis

Physical Sciences → Chemical Engineering → Process Chemistry and Technology

Asymmetric Hydrogenation and Catalysis

Physical Sciences → Chemistry → Inorganic Chemistry

Organometallic Complex Synthesis and Catalysis

Physical Sciences → Chemistry → Organic Chemistry

Carbonylation of methanol in supercritical CO2 catalysed by a supported rhodium complex

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