JOURNAL ARTICLE

‘Revised’ mass spectral identification of 2-amino-4-(5-nitro-2-furyl)thiazole metabolites

Abstract

The electron ionization mass spectra of 2-amino-4-(5-nitro-2-furyl)thiazole metabolites obtained from microsomal incubations and chemical syntheses were studied. The identities of the metabolites were established by chemical ionization, high resolution, and metastable measurements. The compounds studied showed multiple modes of cleavage, skeletal rearrangements and hydrogen back-transfer.

Keywords:
Thiazole Chemistry Nitro Ionization Electron ionization Mass spectrum Chemical ionization Metastability Mass spectrometry Cleavage (geology) Chemical structure Stereochemistry Organic chemistry Chromatography Ion Materials science

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Topics

bioluminescence and chemiluminescence research
Life Sciences →  Biochemistry, Genetics and Molecular Biology →  Molecular Biology
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