New layered cobalt oxyfluoride, Sr<sub>2</sub>CoO<sub>3</sub>F

Yoshihiro Tsujimoto; Jun J. Li; Kazunari Yamaura; Yoshitaka Matsushita; Yoshio Katsuya; Masahiko Tanaka; Yuichi Shirako; Masaki Akaogi; E. Takayama‐Muromachi

doi:10.1039/c0cc05482h

JOURNAL ARTICLE

New layered cobalt oxyfluoride, Sr₂CoO₃F

Yoshihiro Tsujimoto Jun J. Li Kazunari Yamaura Yoshitaka Matsushita Yoshio Katsuya Masahiko Tanaka Yuichi Shirako Masaki Akaogi E. Takayama‐Muromachi

Year: 2011 Journal: Chemical Communications Vol: 47 (11)Pages: 3263-3265 Publisher: Royal Society of Chemistry

DOI: 10.1039/c0cc05482h

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Abstract

The first Ruddlesden-Popper type layered cobalt oxyfluoride, Sr(2)CoO(3)F, has been synthesized under a pressure of 6 GPa at 1700 °C and shown to adopt a K(2)NiF(4)-type structure with distorted square pyramidal coordination around Co and with O/F disorder at the apical sites.

Keywords:

Cobalt Crystallography Square pyramidal molecular geometry Materials science Type (biology) Chemistry Inorganic chemistry Crystal structure Geology

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Inorganic Fluorides and Related Compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Magnetic and transport properties of perovskites and related materials

Physical Sciences → Materials Science → Electronic, Optical and Magnetic Materials

Advanced Condensed Matter Physics

Physical Sciences → Physics and Astronomy → Condensed Matter Physics

New layered cobalt oxyfluoride, Sr₂CoO₃F

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