Hexaaquamanganese(II) dichloride 4,4′-bipyridine<i>N</i>,<i>N</i>′-dioxide disolvate dihydrate

Hui‐Hua Song; Bao‐Qing Ma

doi:10.1107/s160053680701001x

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Hexaaquamanganese(II) dichloride 4,4′-bipyridineN,N′-dioxide disolvate dihydrate

Hui‐Hua Song Bao‐Qing Ma

Year: 2007 Journal: Acta Crystallographica Section E Structure Reports Online Vol: 63 (4)Pages: m1010-m1012 Publisher: International Union of Crystallography

DOI: 10.1107/s160053680701001x

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Abstract

The asymmetric unit of the title compound, [Mn(H2O)6]Cl2·2C10H8N2O2·2H2O, consists of one half of the [Mn(H2O)6]2+ cation, with the Mn atom on a centre of inversion, a chloride anion, a 4,4′-bipyridine N,N′-dioxide solvate and a solvent water molecule. 4,4′-Bipyridine N,N′-dioxide molecules link [Mn(H2O)6]2+ cations through O—H⋯O hydrogen bonds into a two-dimensional sheet. These sheets are further connected by solvent water molecules and Cl− anions into a three-dimensional network via O—H⋯Cl and O—H⋯O hydrogen bonds.

Keywords:

Chemistry Hydrogen bond Solvent Chloride Ion Bipyridine Medicinal chemistry Inorganic chemistry Crystallography Crystal structure Molecule Organic chemistry

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Crystal structures of chemical compounds

Physical Sciences → Chemistry → Inorganic Chemistry

Metal-Organic Frameworks: Synthesis and Applications

Physical Sciences → Chemistry → Inorganic Chemistry

Crystallography and molecular interactions

Physical Sciences → Chemistry → Physical and Theoretical Chemistry

Hexaaquamanganese(II) dichloride 4,4′-bipyridineN,N′-dioxide disolvate dihydrate

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